Thermoplastic Composites

Due to their outstanding properties, fiber-reinforced plastics (FRP), also known as composites, are already extremely relevant in numerous applications. Until now, composites made of combinations of continuous glass fibres (GFRP) or carbon fibres (CFRP) with a thermoset polymer matrix such as epoxy resin, so-called fibre-reinforced thermosets, have mostly been used. However, thermosets as matrix materials cannot meet the high demands of high-end applications in all cases. 
A family of advanced composites offers more diverse application possibilities: thermoplastic composites. These are fibre-reinforced plastics that have a thermoplastic matrix instead of a thermoset matrix, also known as fiber-reinforced thermoplastic (FRTP). Thermoplastic composites consist of two components: A continuous fibre reinforcement, usually made of carbon or glass fibres, and a matrix material made of thermoplastic. The combination allows the advantageous properties of the two components to be exploited.
The type of fibre and the fibre architecture of the reinforcement material used can be customised to the application. Almost all thermoplastic polymers can be used as matrix material, from commodities such as polypropylene to high-performance plastics such as PEEK. In addition to the familiar carbon or glass fibres, other fibre types such as aramid, basalt or natural fibres can also be used as reinforcements.
The Ensinger Composites portfolio includes a wide range of different engineering and high-temperature plastics with continuous fibre reinforcement made of carbon fibres, glass fibres, synthetic or natural fibres. From materials such as prepregs and organosheets to stock shapes such as plates or even customised products – our experts will accompany you with expertise and many years of experience in the field of high-quality composite solutions. 


Product Portfolio

Prepreg and Semipreg

Ensinger TECATEC prepregs
Thermoplastic prepregs and semipregs are manufactured by us in various polymer and fabric combinations.

Organosheets

Thermoplastic organosheets are manufactured from prepreg, semipreg or using the film stacking process, whereby we can individually adapt the components used to your application.

Composite Plates

Sheets of thermoplastic fibre composites can be supplied in thicknesses from 1 mm to 55 mm in dimensions up to 1200 x 900 mm and in thicknesses up to 95mm in a size of 500 x 600 mm.
Most thermoplastic matrix materials are offered.

Composite Parts

Bike crank made from thermoplastic composites
Thermoplastic fibre composites can be used in a variety of ways. While organosheets are ideal for flat components, thermoplastic composites can also be used to produce geometrically complex or even hollow structures using the right processes and tools. We support you from the idea to prototype production.

Material combinations

High performance thermoplastic fibre composites are available in a wide range of material combinations, allowing the composite to be tailor-made to suit the application:

High-performance matrix materials

  • Polyetheretherketone (PEEK)
  • Polyetherketoneketone (PEKK)
  • Polyetherimide (PEI)
  • Polyphenylene sulphide (PPS)
  • Polyether sulfone (PES)
  • Low-melt polyaryletherketone (LM-PAEK)

Engineering matrix materials

  • Polyamide 6 (PA 6)
  • Polyamide 66 (PA 66)
  • Polyphthalamide (PPA/PA9T)
  • Polyoxymethylene (POM)
  • Polybutylene terephthalate (PBT)
  • Bio-based, biodegradable polymers

Industrial matrix materials

  • Polycarbonate (PC)
  • Polypropylene (PP)
  • Styrene acrylonitrile (SAN)

GFRP: Glass fibre reinforced plastic

Several different glass fibre weave patterns are available:
  • Plain
  • Twill 2/2
  • US7781
  • BiMax +/-45°

CFRP: Carbon fibre reinforced plastic

Different carbon fibre fabrics are available:

  • Plain
  • Twill 2/2
  • Satin 5HS
  • BiMax +/-45°
  • UD weave
  • Veil/Fleece

Other reinforcing materials 

  • Synthetic fibres such as aramide, PA66, PET
  • Natural fibre fabrics such as basalt or flax

Ensinger also offers composites materials with special plastics, formulations and blends, including:

  • Medical Grade PEEK
  • Flame-resistant polycarbonate for use in aircraft interiors
  • Composites with low-melting polyaryletherketone PAEK (LM-PAEK) 

For other materials and combinations, please do not hesitate to ask us.


Production of our materials

The process of composite manufacturing begins with the grinding of the plastic granulate. The spectrum of thermoplastic polymers that can be ground into powders in-house ranges from engineering plastics such as PP, PA6 and PC to high-performance plastics such as PPS, PEI and PEEK. With their tight tolerances, the powdered materials meet the high demands placed on the application of modern composites.

The powder is then applied to textile semi-finished products, for example carbon or glass fibre fabrics, in the prepreg plant and subsequently melted and pressed. The resulting semi-finished product is called semipreg.  

If the semipreg is then consolidated and impregnated by a double belt or step press, it is referred to as a prepreg. An organosheet is a multi-layer composition of prepregs that are consolidated.

Further processing of the semipreg materials into prepregs and organosheets takes place on Ensinger's own double belt press. With a working width of up to 1800 mm, the double belt press processes not only Ensinger's own thermoplastic semipregs but also unidirectional (UD) materials, UD cross-ply materials, laminates and sandwich laminates with various core materials such as foam or honeycomb. Various combinations of textiles and polymer matrix materials can be realised, including carbon, glass, aramid and natural fibres. Thermoplastic composites can thus be produced in high quantities on the double belt press. 

Ensinger Group’s new double-belt press
We support our customers in the further processing of our materials. With over 15 years of experience in component and process development in the field of thermoplastic composites, we can offer you a customised solution for your application. 

Advantages & characteristics of composites

 Thermoplastic fibre composites have unique properties and many advantages over non-reinforced and short-fibre reinforced plastics as well as fibre-reinforced thermoset materials. 
  • Due to their significantly higher impact strength and thus higher damage tolerance, thermoplastic composites are much more suitable for applications in harsh environments than thermosets. In addition, the high elongation at break of thermoplastics provides a tough, non-brittle fracture behaviour. For some applications, the inherent vibration damping of the matrix can also be a relevant advantage.
    Graph: impact strength thermoplastic composites
  • The use of fibre-reinforced plastics allows a much lower weight compared to metals and metal alloys with the same stiffness or strength. By using continuous, oriented fibres (e.g. unidirectional or woven), fibre-reinforced plastics have a much higher specific strength and stiffness than short-fibre reinforced or unreinforced plastics. Plates of thermoplastic composites, for example, have a density between 1.3 and 1.8 g/cm³ and thus a similar specific weight to unreinforced or short-fibre reinforced sheets. However, due to the reinforcing fibres, the mechanical properties are drastically increased and reach a metal-like level. For example, compared to non-reinforced polymer sheets, continuous fibre-reinforced sheets achieve, 5 times higher values for tensile strength and modulus of elasticity.
  • Layup sequence and local reinforcements can be customised to the requirements of the respective project. Shape and fibre direction can also be customised.
  • While metals cannot be used in all applications, thermoplastic composites – depending on the polymer used – are particularly resistant even in harsh environments. PPS and PEEK are especially suitable here. We will be happy to advise you on your individual application, resorting to over 50 years of experience in the field of thermoplastics. Depending on the application, polymers with high chemical or physical resistance or low moisture absorption are used.
  • Thermoplastics retain their mechanical properties even at elevated temperatures – thermoplastic composites are therefore stable and reliable even in demanding thermal environments. Continuous fibre reinforced thermoplastics have extremely low coefficients of thermal expansion (CTE) in the range of about 5x10-6 K-1. This property is of great importance for applications where the components are exposed to temperature fluctuations over a wide range and high precision is required.
  • Compared to unreinforced or short-fibre-reinforced polymers, continuous-fibre-reinforced materials have a significantly higher creep resistance and thus also improved fatigue behaviour.
  • Thermoplastic fibre composites have excellent vibration damping properties due to their intrinsic self-damping properties. This can be particularly advantageous in applications where vibrations need to be filtered.

Advantages in the processing of thermoplastic composites

  • High-performance thermoset resins often take several hours to cure and require a lot of manual effort in the manufacturing process. Thermoplastic composites do not require chemical curing and can therefore reduce process times to just a few minutes. Thermoplastic composites enable automated manufacturing and make it possible to produce high volumes with consistent quality. This means that high-quality series production is possible.
  • Thermoplastic composites can be stored and transported at room temperature. In addition, they can be stored indefinitely.
  • Fiber-reinforced thermoplastics soften when the composite parts are heated to high temperatures. They can be formed and welded quickly and repeatable.
  • Thermoset composites cure permanently due to the chemical cross-linking mechanism and thus cannot be reused. Thermoplastic composites offer advantages in terms of resource-saving material use: the material can be reused by melting and, if necessary, chipping and thus offers an opportunity for material recycling, both at material and component level.
  • No VOCs are released during the processing of composite thermoplastic materials, because the materials are solvent-free.