TECATRON CMP natural

PPS UNFILLED TUBES FOR CMP RETAINING RINGS

TECATRON CMP natural is an unfilled PPS plastic (polyphenylene sulfide) optimized specifically for CMP retaining ring applications and is thus part of Ensinger's portfolio for the semiconductor industry. TECATRON CMP natural is characterised by a unique property profile that enables reduced micro scratches and wafer level defects than standard PPS polymer, when used as CMP retaining rings. The former name of TECATRON CMP natural has been TECATRON SE natural. 

A key challenge in material selection is that minor differences in the material properties of the CMP retaining ring will impact the shape of the pad asperities. This modification will cause different amounts of pad fragments and influence the extent of fragment entrainment, which in turn has a significant impact on the overall performance of the CMP process. Studies have shown that TECATRON CMP wears the pads in a manner so that the pad asperities are optimized for enhanced material removal as well as reduced defects. (See study, the product is called TECATRON SE in the article, which is the former name of TECATRON CMP) 

As with all Ensinger semiconductor grades, TECATRON CMP natural tubes are processed in compliance with semiconductor copy exactly requirements (also known as copy exact or CE) and more stringent quality controls compared to industrial PPS grades.
Additional quality controls and measures enable reduced risks of impurities and improved internal stress and dimensional stability compared to standard industrial PPS materials.

Besides the optimizations of material properties, Ensinger has also developed special tube sizes that better fit typical sizes of CMP retaining rings, thus enables reduction of waste and costs during machining. For example, using the tube size with O.D. 350 mm / I.D 300 mm saves up to 27 % material costs compared to conventional O.D. 360 / I.D. 290 mm.

For CMP retaining rings that require more enhanced lifetime, Ensinger offers an unfilled PEEK based TECAPEEK CMP natural, also with a special property profile aligned to CMP retaining rings. For other semiconductor PPS applications that do not require this special property profile, Ensinger offers a more cost-efficient semiconductor grade PPS plate, rod, and tubes – TECATRON SX natural.

 

Facts

Chemical designation
PPS (Polyphenylensulfide)
Color
beige
Density
1.36 g/cm3

Main Features

  • good heat deflection temperature
  • good chemical resistance
  • resistance against high energy radiation
  • high strength
  • high dimensional stability
  • high stiffness
  • high creep resistance

Target industries

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Technical details


  • product-technical-detail-collapse-item-0-lvl-1
    Mechanical properties Value Unit Condition Test Method
    Modulus of elasticity
    (tensile test)
    673,400 psi @73°F ASTM D 638
    Compression modulus 484,200 psi ASTM D 695
    Impact strength (Izod) 0.55 ftlbsin @73°F ASTM D 256
    Tensile strength at break 13,920 psi @73°F ASTM D 638
    Tensile strength 13,980 psi @73°F ASTM D 638
    Flexural strength 22,040 psi @73°F ASTM D 790
    Elongation at break (tensile test) 4.2 % @73°F ASTM D 638
    Modulus of elasticity
    (flexural test)
    636,000 psi @73°F ASTM D 790
    Rockwell hardness 103.3 - M scale ASTM D 785
    Compression strength 5,500 psi @ 10% strain ASTM D 695
    Compression strength 19,960 psi @ 1% strain ASTM D 695
  • product-technical-detail-collapse-item-1-lvl-1
    Thermal properties Value Unit Condition Test Method
    Glass transition temperature 194 F DIN EN ISO 11357
    Melting temperature 536 F DIN EN ISO 11357
    Thermal expansion (CLTE) 2.8 *10^-5 in/in / degre ASTM E 831
    Deflection temperature 239 F @ 264 psi ISO-R 75 Method A
    Deflection temperature 320 F @ 65 psi ISO-R 75 Method B
    Service temperature 500 F short term -
    Service temperature 446 F long term -
  • product-technical-detail-collapse-item-2-lvl-1
    Electrical properties Value Unit Condition Test Method
    Dielectric constant 2.8 - @ 1 kHz DIN IEC 60250
    Dielectric constant 4.6 - @ 1 MHz DIN IEC 60250
    Dissipation factor 0.0011 - @ 1 MHz DIN IEC 60250
  • product-technical-detail-collapse-item-3-lvl-1
    Other properties Value Unit Condition Test Method
    HZ-Catalogue no - -
    HZ Semicon brochure yes - -
    Resistance to hot water/ bases + - -
    Flammability (UL94) V0 - @ 3 mm -
    Resistance to weathering - - -
    Water absorption 0.02 % @ 24 hrs ASTM D 570

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